Thermodynamics links what you can measure, such as pressure and temperature, to the motion of countless gas atoms. The unit covers the kinetic model, the ideal gas law, how energy moves between systems, the first law with PV diagrams, specific heat and conduction, and a qualitative look at entropy. It is 15–18% of the multiple-choice section.
- gas pressure (kinetic model)
- Gas atoms collide with the walls and push on them. Pressure is the total perpendicular force divided by the area, P = F⊥/A, and it exists throughout the gas.
- Example: A total perpendicular force of 1,000 N on a 0.010 m² piston gives P = 1,000 N/0.010 m² = 100,000 Pa.
- ideal gas (model)
- A model gas: the atoms move with random velocities, take up negligible volume, collide elastically, and exert forces on each other only during collisions.
- Example: Room-temperature air in a bicycle tire behaves very nearly like an ideal gas.
- heating and cooling (thermal contact)
- Systems are in thermal contact when energy can pass between them by thermal processes. Heating is energy transferred into a system this way; cooling is energy transferred out.
- Example: A cold juice box set on a warm counter: the juice is heated while the counter beneath it is cooled.
- internal energy
- Kinetic energy of a system's particles plus potential energy of their configuration (an ideal gas has none). It can change without moving the system's center of mass.
- Example: Ice melting at 0 °C gains internal energy as configuration potential energy, though its temperature stays the same.
- isothermal process
- A process at constant temperature, following an isotherm on a PV diagram. For an ideal gas, U doesn't change (ΔU = 0), so Q = −W.
- Example: Slowly compressing a gas in a cylinder kept in an ice bath: 300 J of work done on it, 300 J leaves by cooling.
- specific heat
- The energy needed to raise 1 kg of a material by 1 K, from Q = mcΔT. It is an intrinsic property of the material, modeled as independent of temperature.
- Example: Warming 0.20 kg of aluminum (c = 900 J/(kg·K)) by 10 K takes Q = (0.20)(900)(10) = 1,800 J.
- entropy
- A qualitative measure of how spread out a system's energy is, or how much of it can't do work. A state function, it is greatest at thermodynamic equilibrium.
- Example: A bouncing ball's energy ends up spread through the floor and air as thermal energy, which can't relaunch the ball.
- temperature (kinetic model)
- Temperature measures the average kinetic energy of the atoms in a system. For an ideal gas, K_avg = (3/2)k_B·T, with T in kelvins.
- Example: Xenon at 300 K: K_avg = (3/2)(1.38 × 10⁻²³ J/K)(300 K) ≈ 6.21 × 10⁻²¹ J per atom.
- ideal gas law
- For an ideal gas, pressure times volume equals the number of moles times R times the kelvin temperature: PV = nRT = Nk_B·T.
- Example: 2.0 mol at 300 K in 0.050 m³: P = (2.0)(8.31)(300)/0.050 ≈ 9.97 × 10⁴ Pa, about 1 atm.
- conduction
- Energy transfer through collisions between atoms of systems in direct contact. Energy passes atom to atom while the material itself stays in place.
- Example: The handle of a metal spoon left in hot soup grows warm as energy passes along the spoon.
- internal energy of an ideal monatomic gas
- For an ideal monatomic gas, internal energy is just the atoms' total kinetic energy: U = (3/2)nRT = (3/2)Nk_B·T, so it depends only on T.
- Example: 2.0 mol of argon at 400 K: U = (3/2)(2.0 mol)(8.31 J/(mol·K))(400 K) ≈ 9,970 J.
- isobaric process
- A process at constant pressure, shown as a horizontal line on a PV diagram. The work done on the gas is W = −PΔV.
- Example: At a steady 1.0 × 10⁵ Pa, a gas shrinks by 0.015 m³ (ΔV = −0.015 m³): W = −PΔV = +1,500 J.